Ungoliant could have served Morgoth at some point in time, and then have "rebelled." I have a feeling that there were many Maiar in Morgoth's "train," and he sort of experimented on them. Ungoliant could have been one of those.
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But Melkor also was there, and he came to the house of Fëanor, and there he slew Finwë King of the Noldor before his doors, and spilled the first blood in the Blessed Realm; for Finwë alone had not fled from the horror of the Dark.
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