No it wasn't. Sam was willing to give Gollum a chance but was continuously antagonised by him. Gollum was isolated based on his own sense of worthlessness. He pushed Frodo and Sam away because subconciously he knew that he deserved to be alone.
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Remember, stranger, passing by: As you are now, so once was I. As I am now, so you shall be. Prepare thyself to follow me.
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