I can think of two reasons for the differences between Sauron and Saruman.
1) Sauron was a greater Ainu and was therefore more powerful in his skills, spells, and personal presence.
2) Sauron fell early and had long ages of being wholly evil. Saruman had been good until perhaps the last 500 years of the Third Age; also, Tolkien depicts him at his "unstaffing" and at his death, as being at war with himself. When there's a civil war in any nation, that nation is far weaker than when unified. The same goes for people.
However, one can distinguish between the listeners of the two. Who was taken in by Sauron, and who not? Same question for Saruman?
One might suspect that Frodo would have been taken in by Saruman at the beginning, but he grew so much that he could see through Saruman in the end. The Eorlingas of Rohan were snowed by him. Theoden had to fight with a will to get his mind cleared enough to speak past the subtle lies, even in the face of recent events! Gimli is not fooled, which I find interesting and very satisfying.
The Numenoreans were tending towards evil anyway, so it is no great surprise that they believed Sauron's lies. It is interesting however that the Elves of Eregion either could not, or refused to, see through his deceptions until it was too late; what does that say of them, as opposed to what it tells us of Sauron?
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