I don't think that Arwen aged, she just went to Lórien and died when Aragorn passed away. Not all elves can choose mortality; the first to have that choice was Lúthien, who had the choice because the Valar gave it to her; the same as Eärendil, Elwing, Elrond and Elros. Methinks that an elf can only chose mortality if they are in love with a mortal, or a half-elf.
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