I'll have to admit, Alan Rickman as the voice of Smaug could work very nicely, but like James Earl Jones, I hear his voice in my head already for too many characters, from Severus Snape to Marvin the Paranoid Android. Ian McDiarmid (Emperor Palpatine/Darth Sidious, in case you've been living in a cave for the last 30 years) is a classically-trained stage actor, and as long as he doesn't go into that "Sidious croak" I think he could pull off a similar quality of sneering disdain, as he did playing the doctor in Sleepy Hollow.
Just my two cents worth.
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The object of life is not to be on the side of the majority, but to escape finding oneself in the ranks of the insane. ~~ Marcus Aurelius
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