My opinion is that Galadriel at the time may not have been as wise, but by the end of the third age was most likely wiser. But I must say that for the most part, Luthien was more powerful.
You have to look into the many different categories that power and wisdom would fall into, for one, Luthien had a powerful voice. But Galadriel was wise and powerful enough to reject the ring. I am not sure how else Tolkien described her but he said that Luthian was the fairest not the wisest or most powerful. But being part Maia and part elf Im sure she had a good deal of both.
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Instead of pepper spray, you pack a glass bottle and scream "Aiya Earendil Elenion Ancalima!!!" at muggers.
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